Rolls-Royce Phantom III
What a great name for a man intent on world domination!
Goldfinger was released in 1964 and the 'baddies' were governed by a man of the same name. With such an extravagant name, it was only fitting that Goldfinger himself was chauffeured around.
The car of choice was the Rolls-Royce Phantom III with a body by Sedance de Ville in which his lordship sat in the rear under a nice roof while his driver was exposed to the elements up front. Not that it rains often on the set of a Bond movie... Unsurprisingly, this car was not involved in a long high-speed chase, which is just as well, as Bond's Aston DB5 would have left it for dead.